1986: Pruzzo's five goals
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Before Klose's performance on May 5, 2013 in Lazio-Bologna 6-0, the last five goals scored by a player in the same Serie A match went back to February 16, 1986 and were scored by Roma forward Roberto Pruzzo, who achieved the feat in the match against Avellino at the Olimpico: it ended 5-1 for the Giallorossi.
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Source: legaseriea.it